a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\); \(n_{HCl}=\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,8}{6}\) => Al hết, HCl dư

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

            0,2-->0,6---->0,2----->0,3

=> V_H2 = 0,3.22,4 = 6,72 (l)

b) \(\left\{{}\begin{matrix}m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\\m_{HCl\left(dư\right)}=\left(0,8-0,6\right).36,5=7,3\left(g\right)\end{matrix}\right.\)

=> m_{chất tan} = 26,7 + 7,3 = 34 (g)

c) m_{dd sau pư} = 5,4 + 200 - 0,3.2 = 204,8 (g)

\(\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{26,7}{204,8}.100\%=13,04\%\\C\%_{HCl\left(dư\right)}=\dfrac{7,3}{204,8}.100\%=3,56\%\end{matrix}\right.\)

\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\) 
           0,2                       0,2       0,3 
\(V_{H_2}=0,3.22,4=6,72L\\ m_{AlCl_3}=133,5.0,2=26,7g\\ m_{\text{dd}}=5,4+200-\left(0,3.2\right)=204,8g\\ C\%=\dfrac{26,7}{204,8}.100\%=13\%\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

a) Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\) \(\Rightarrow n_{HCl}=0,2mol\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,2\cdot36,5}{10,95\%}\approx66,67\left(g\right)\)

b) Theo PTHH: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,1mol\)

\(\Rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,1\cdot136=13,6\left(g\right)\\m_{H_2}=0,1\cdot2=0,2\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Zn}+m_{ddHCl}-m_{H_2}=72,97\left(g\right)\)

\(\Rightarrow C\%_{ZnCl_2}=\dfrac{13,6}{72,97}\cdot100\%\approx18,64\%\)

1.

\(m_{HCl}=\dfrac{10,95.75}{100}=8,2125\left(g\right)\)

\(\Rightarrow n_{HCl}=\dfrac{8,2125}{35,5}=0,225\left(mol\right)\)

\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)

\(\Rightarrow n_{Fe_2O_3}=\dfrac{1}{6}n_{HCl}=0,0375\left(mol\right)\)

\(n_{FeCl_3}=\dfrac{1}{3}n_{HCl}=0,075\left(mol\right)\)

\(\Rightarrow C\%=\dfrac{0,075.162,5}{0,0375.160+75}.100\%=15,05\%\)

2.

\(n_{Al_2O_3}=0,1\left(mol\right);n_{HCl}=0,8\left(mol\right)\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

Dễ thấy HCl dư.

\(\Rightarrow n_{AlCl_3}=2n_{Al_2O_3}=0,2\left(mol\right)\)

\(\Rightarrow m_{AlCl_3}=26,7\left(g\right)\)

\(\Rightarrow C\%=\dfrac{26,7}{10,2+200}.100\%=12,7\%\)

\(n_{FeO}=\dfrac{14,4}{72}=0,2\left(mol\right)\)

\(m_{ct}=\dfrac{10,95.200}{100}=21,9\left(g\right)\)

\(n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)

Pt : \(FeO+2HCl\rightarrow FeCl_2+H_2O|\)

         1           2             1            1

        0,2       0,6            0,2

a) Lập tỉ số so sánh : \(\dfrac{0,2}{1}< \dfrac{0,6}{2}\)

             ⇒ FeO phản ứng hết , HCl dư

             ⇒ Tính toán dựa vào số mol của FeO

\(n_{HCl\left(dư\right)}=0,6-\left(0,2.2\right)=0,2\left(mol\right)\)

⇒ \(m_{HCl\left(dư\right)}=0,2.36,5=7,3\left(g\right)\)

b) \(n_{FeCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{FeCl2}=0,2.127=25,4\left(g\right)\)

\(m_{ddspu}=14,4+200=214,4\left(g\right)\)

\(C_{FeCl2}=\dfrac{25,4.100}{214,4}=11,85\)⁰/₀

\(C_{HCl\left(dư\right)}=\dfrac{7,3.100}{214,4}=3,4\)⁰/₀

 Chúc bạn học tốt

a,\(n_{FeO}=\dfrac{14,4}{72}=0,2\left(mol\right)\)

 \(m_{HCl}=10,95\%.200=21,9\left(g\right)\Rightarrow n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)

PTHH: FeO + 2HCl → FeCl₂ + H₂O

Mol:      0,2      0,4         0,2

Ta có: \(\dfrac{0,2}{1}< \dfrac{0,6}{2}\) ⇒ FeO pứ hết ,HCl dư

m_{HCl dư} = (0,6-0,4).36,5 = 7,3 (g)

b, \(m_{FeCl_2}=0,2.127=25,4\left(g\right)\)

c, m_{dd sau pứ} = 14,4+200 = 214,4 (g)

\(C\%_{ddFeCl_2}=\dfrac{25,4.100\%}{214,4}=11,847\%\)

\(C\%_{ddHCldư}=\dfrac{7,3.100\%}{214,4}=3,4\%\)

a)       2Al + 3H₂SO₄  →  Al₂(SO₄)₃   +  3H₂

nH₂SO₄ = 0,2.1,5= 0,3 mol

nAl = \(\dfrac{5,4}{27}\) = 0,2 mol

Ta có \(\dfrac{nAl}{2}\)= \(\dfrac{nH_2SO_4}{3}\) => phản ứng vừa đủ , Al và H₂SO₄ đều hết. 

nH₂ = nH₂SO₄ = 0,3 mol => V H₂ = 0,3.22,4 = 6,72 lít

b) vì Al và H₂SO₄ đều phản ứng hết => dung dịch sau phản ứng chỉ gồm Al₂(SO₄)₃  0,2 mol

=> [Al₂(SO₄)₃] = \(\dfrac{0,2}{0,2}\) = 1M

\(n_{CaO}=\dfrac{14}{56}=0,25\left(mol\right)\)

\(m_{ct}=\dfrac{10,95.200}{100}=21,9\left(g\right)\)

\(n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)

Pt : \(CaO+2HCl\rightarrow CaCl_2+H_2O|\)

          1           2             1            1

         0,25     0,3          0,15

a) Lập tỉ số so sánh : \(\dfrac{0,25}{1}>\dfrac{0,3}{2}\)

                  ⇒ CaO dư , HCl phản ứng hết

                 ⇒ Tính toán dựa vào số mol của HCl

\(n_{CaCl2}=\dfrac{0,3.1}{2}=0,15\left(mol\right)\)

⇒ \(m_{CaCl2}=0,15.111=16,65\left(g\right)\)

b) \(m_{ddspu}=14+200=214\left(g\right)\)

\(C_{CaCl2}=\dfrac{16,65.100}{214}=7,78\)⁰/₀

 Chúc bạn học tốt

PTHH: \(K_2SO_3+2HCl\rightarrow2KCl+H_2O+SO_2\uparrow\)

a+b+c) Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{KCl}=0,5\left(mol\right)=n_{HCl}\\n_{K_2SO_3}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_3}=0,25\cdot158=39,5\left(g\right)=a\\m_{KCl}=0,5\cdot74,5=37,25\left(g\right)\\m_{ddHCl}=\dfrac{0,5\cdot36,5}{10,95\%}\approx166,67\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{SO_2}=0,25\cdot64=16\left(g\right)\)

\(\Rightarrow m_{dd}=m_{K_2SO_3}+m_{ddHCl}-m_{SO_2}=190,17\left(g\right)\) \(\Rightarrow C\%_{KCl}=\dfrac{37,25}{190,17}\cdot100\%\approx19,59\%\)

d) PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)

Theo PTHH: \(n_{NaOH}=n_{HCl}=0,5\left(mol\right)\) \(\Rightarrow V_{NaOH}=\dfrac{0,5}{0,5}=1\left(l\right)\)

\(a)n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ 2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot0,4=0,6\left(mol\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\\ b)n_{HCl}=3n_{Al}=3.0,4=1,2\left(mol\right)\\ m_{HCl}=1,2.36,5=43,8\left(g\right)\\ m_{dd_{HCl}}=\dfrac{43,8}{10,95\%}\cdot100\%=400\left(g\right)\\ c)n_{AlCl_3}=n_{Al}=0,4mol\\ m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\\ m_{H_2}=0,6.2=1,2\left(g\right)\\ m_{dd_{AlCl_3}}=10,8+400-1,2=409,6\left(g\right)\\ C_{\%AlCl_3}=\dfrac{53,4}{409,6}\cdot100\%\approx13\%\)